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KMID : 1059519990430050505
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Journal of the Korean Chemical Society
1999 Volume.43 No. 5 p.505 ~ p.510
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Synthesis of TiO2 Powders by the Hydrolysis of Titanium n-Butoxide and Reaction mechanism
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Park J.-K.
Myung J.-J.
Chung Y.-S.
Kyong Jin-Burm
Kim Ho-Kun
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Abstract
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TiO2 powders were prepared via hydrolysis of titanium n-butoxide in n-butanol and hydrolysis mechanism of titanium n-butoxide was studied using UV-Vis spectrometer. Hydrolysis reactions were controlled to proceed to pseudo-first order reaction in the presence of excess water. The phases of TiO2 powders, prepared under the these conditions, were identified by XRD and reaction rates were calculated by Gugggenheim method. Prepared powders were noncrystalline states in their initial stage of formation but transformed to crystalline rutile structure by heating. Reaction mechanism of titanium n-butoxide was proposed as Interchange-Associative(Ia) mechanism, based on the data of n-value and termodynamic parameters which were determined from the rate constants.
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KEYWORD
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